how to find concentration of naoh with khp

6. A concentrated solution of sodium hydroxide acts as a buffer (albeit a very alkaline one) since adding small quantities will not change the pH significantly--the acid will only react with the sodium hydroxide that was already present in the water, and the pH will not change significantly since pH is a logarithmic scale. We mix both substances in one Erlenmeyer. The number of moles of NaOH is found by multiplying the moles of KHP by the mole ratio of NaOH to KHP given by the above, balanced chemical reaction. I said "you must assume that the volumes are additive." Potassium hydrogen phthalate, KHC8H4O4 (abbreviated KHP), is a non-hygroscopic, crystalline, solid that behaves as a monoprotic acid. 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