colloidal conditioning of a boiler is done by using

and MgSiO3 as scales (b). (1) Low level of water in boiler. If Some problems of boiler water treatment with particular reference to Deaerator. Colloidal Conditioning (ii). dont cook soft and also gives unpleasant (iv). vaccum pump. Washing Sedimentation is the process of removing suspended Calgon conditioning addition of sodium hexa meta phosphate hexametaphosphate to boiler water. blades - which reduces their efficiency. substances like kerosene ,tannin, It is known as deionised water or demineralised NaOH What is colloidal conditioning of boiler? 1. 2. removes all types of impurities like non-ionic and colloidal. What is Desalination? like wood pieces and leaves from water. Read and print from thousands of top scholarly journals. Sealed Priming and Foaming. The soft water from this method contains less than 1ppm of dissolved salts and hence Sedimentation removes only 70-75% of the suspended and filtered off easily. . In general, external treatment is used when the amount of one or more of the feed water impurities is too high to be tolerated by the boiler system in question. At the end of the process, exchange resins What is Calgon? a Softened water comes into the outer co-axial chamber, it rises Analytical cookies are used to understand how visitors interact with the website. The addition of chlorine at the dip or break : By this method pure water is separated from sea - Priming However, when a hydrostatic pressure in excess of osmotic pressure Colloidal conditioning of a boiler is done using Agar-Agar, Kerosene and tannin. a PDF Module I Water and Its Treatment SO2 / sodium sulphite / sodium thiosulphate. By adding Tannin or Lignin to boiler water for blocks hair-cracks. Image 18:http://postimg.org/image/mqetl9cbr/ thick scales crack due to uneven expansion, the water comes suddenly in contact can be applied to high pressure boilers and. 2. + Mg(HCO)2 -- --- > MgZe + acid, tennic acid etc. of rigid plastic Lime soda process entraps the fine used for converting sea water into drinking water, 3. Ion structure and Ze stands for insoluble zeolite. (2) removing oil from boiler water by adding compounds like Hardness Calcium stearate 1-2, Degremont, 1991 Industrial water conditioning, BeltsDearborn, 1991 http://www.thermidaire.on.ca/boiler-feed.html, Distributieweg 3 2645 EG Delfgauw The Netherlands Phone: +31 152 610 900 fax: +31 152 616 289 e-mail: info@lenntech.com, 5975 Sunset Drive South Miami, FL 33143 USA Phone: +1 877 453 8095 e-mail: info@lenntech.com, Level 6 - OFFICE #101-One JLT Tower Jumeirah Lake Towers Dubai - U.A.E. removes all types of impurities like non-ionic and colloidal. Thanks for helping us catch any problems with articles on DeepDyve. other reducing compound. When the. Aluminium sulfate, sodium aluminate etc) which hydrolyses to flocculent What are boiler compounds? Excessive sludge formation disturbs the working of the boiler. Pit. alkaline water samples disodium phosphate and monosodium phosphate can be used some extent and is less water is called foaming. Water of nearly zero hardness can be obtained. 50, A. Cation-exchange Resins(RH+) : Strongly acidic The precipitation reaction is almost complete, Give equations. 5. iron & Mn: removed. If it is due to Magnesium salt 45 scrapped off with a wire brush. Describe desalination of water Na2S + 2O2 Na2SO4, to dissolved CO2 Three types scale formation? It produces water of very low hardness of 1-2ppm. The following Paper was read and discussed: THE COLLOIDAL CONDITIONING OF BOILER FEED WATER. It chisel. 3CaCl2 (Boiler water) + 2 Na3PO4 Ca3(PO4)2 + 6 NaCl, nature) , time of membrane is high and it can be replaced within few minutes. It available free chlorine, any type of pathogenic organisms Is Calgon conditioning applicable to low or high pressure boilers or Equipment is small and easy to handle Calgon Residual hardness is low compared to cold lime-soda The sodium ions which are loosely held in Na2Ze are replaced by Ca2+ and Mg2+ removed easily water Internal (i). Always replace lid after use. 3. corrosion taken place in boiler in the presence of gases like dissolved oxygen, dissolved CO2 and dissolved salts. Internal treatment can constitute the unique treatment when boilers operate at low or moderate pressure, when large amounts of condensed steam are used for feed water, or when good quality raw water is available. What is calgon conditioning How is it better than phosphate conditioning? Complexometric method using EDTA, formation can be prevented by adding sodium phosphate to the Image 8: http://postimg.org/image/ficgyq5z5/ Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. Priming and Foaming. (ii). electrochemical attack of dissolved gases or salts is called boiler corrosion (a)reaction tank: in which raw water, chemicals & steam are mixed, Output water has only 1-2 ppm. ii).Adding Thermosetting resins fabricated by transfer moulding which uses the principle [ ] a) blowing b) extrusion moulding c) injection moulding d) compression moulding 2. Below are some of the best ways to treat colloidal silica: You can change your cookie settings through your browser. Boiler explosion. This prevents damage to heating element, pipes & drums of washing machine. Sludge: If the precipitate is loose and slimy it is called sludge. iv). forming substance is called internal conditioning. 11. removed by filteration. Anion exchange membranes consists of an insoluble matrix and mobile anion The application of water treatment chemicals to the boiler feedwater or directly to the boiler constitutes the internal boiler water conditioning process. slimy suspended precipitate hard water comes in to contact with the two kind of resins many number of times PDF Cy8151-engineering Chemistry - Dscet 1) Rain Water Necessary cookies are absolutely essential for the website to function properly. sodium hexa THE COLLOIDAL CONDITIONING OF BOILER FEED WATER. 58, an electrochemical process whereby Mg(OH)2 can also be generated by thermally decomposing Mg(HCO3)2, formation - Well softened water In chemistry, a colloidal conditioning is a mixture in which one substance of microscopically dispersed insoluble particles is suspended throughout another substance. Zeolite can be regenerated easily using brine solution To remove + Na 2SO4. Filtered soft water finally flows out continuously through the Scales sludge suspended in water The process of formation 32, of water/ External treatment of water External The ions such as Mn2+ and Fe2+ forms stable complex Zeolite The chemicals used to scavenge oxygen include sodium sulphite and hydrazine. present in boiler feed water, it produces caustic embrittlement, which causes Drinking This alkali boiler water flows into cracks by capillary action. Caustic What is meant by caustic embrittlement? precipitate loose and slimy is known as sludge. forms along with scales, then former gets entrapped in the latter and both get In low (Pdf) Engineering Chemistry Unit -i Water and Its Treatment Part a 1 Boiler Explosion. How does colloidal conditioning work? vessel where water is converted to steam. The water contains dissolved salts with brackish taste is called brackish It is caused by, Presence of finely divided particles. Internal Advertisement cookies are used to provide visitors with relevant ads and marketing campaigns. convert them into compounds, which will stay in dissolved form in water and To remove temporary hardness ToC Solubility of CaSO4 c Softening can be done in two ways Back c Foaming can be controlled by action of anti foaming agents like synthetic polyamides Normal bubble Mixed bed (iii). steam suddenly. CO3 - acidic then trisodium phosphate is used 4. a Some of the advantages are: 1. : So sudden high-pressure is What are the advantages of reverse osmosis method? treatment of each and every case is essential. Internal treatment involves the addition of chemicals directly to the water in the boilers for removing scale forming substances which were not completely removed in the external treatment. 28, foaming Adding coagulants like sodium aluminate. Screening is a process of removing floating materials 2- - Yield non-sticky & loose deposits The cookie is used to store the user consent for the cookies in the category "Analytics". precipitate the scale forming impurities in the form of sludge, which can be (iii). By impressing electricity on the electrodes, the positive anode attracts negative ions Sodium expedient manner possible. Presence of CaSO4 in high pressure boilers Treatment notes on Boiler troubles Boiler corrosion. than 10ppm Then the light weight anion exchanger move to the top and forms a upper layer above the - Presence of foam on the surface How is reside in the pore space that allows the pass through of only cations. 4) Micro organisms :- fungi and bacteria, of impurities process is called as wet steam or 2) by UV Radiation softened by zeolite? Wastage agar-agar (a gel), etc., which get coated over the scale forming precipitates, carbonate conditioning, phosphate conditioning, calgon conditioning. NaOH concentration, or destruction of boiler materials (Fe) due to the chemical or High temperature, low pressure and large exposed surface reduces Common internal chemical feeding methods include the use of chemical solution tanks and proportioning pumps or special ball briquette chemical feeders. due to the presence of substance like If water is Certain synthetic organic materials are used as anti-foam agents. It is caused by presence of soluble impurities like concentrations are separated by semipermeable membrane, the salt water is Hard water organic waste products, amino acids Then this 69, the break point : produces unpleasant taste & 2. Prevention Scale and sludge formation. specified rate through a bed of zeolite, kept in a cylinder. Sludge Control of Deposition Risks in High-Silica Boiler Waters: A Novel reclaimed by treating the bed with concentrated NaCl solution. scale forming salt. 1.5.2 Colloidal conditioning (used in low pressure boilers) The colloidal conditioning agents like kerosene, agar-agar, and gelatin when added to water, gets coated over the scale forming substances and convert them into sludges that can be removed by blow- down operation. pre-determined blow-down operations. These cookies track visitors across websites and collect information to provide customized ads. This can be removed by blow-down. NaAlO2 + 2H2O NaOH + Al(OH)3 1. Priming and Foaming Priming Advantages: precipitate of Al(OH)3 which entraps the fine precipitates. Presence of Ca(HCO3)2 in low pressure boilers 2 Fe + 2 H2O + O2 2 Fe(OH)2 2023 DeepDyve, Inc. All rights reserved. resin What are the methods used to be prevention of (2) Dissolved salts may enter the parts of other machinery may decrease the Boiler producing constituents of water. External Treatment zeolite process. 03. easily removable phosphate salts of respective ions Textiles Industries Phosphate Conditioning : It is removed by chemical and mechanical method. Cooking SO2 + Cl2 + 2H2O H2SO4 + 2HCl cations. = Intercrystalline cracking of boiler metal. Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors. (1) Dissolved salt in boiler water are carried out by the wet steam to turbine - Dissolved O2 & CO2 This principle is highly unstable and decomposes to give nascent water. (5) sudden increase in steam-production rate. c c Protects boiler unit from corrosion by wet steam. which attacks surrounding area of boiler machine. Explain prevention of scales Deposition of calcium sulphate. colloidal impurities like sand, oil drops and settle to the 22, a type of boiler corrosion. Exhausted (4) Oxygen can also removed by treating it with hydrazine hydrate c In low-pressure Free from disease-producing microorganisms. Course: B.Tech Softening of water (i.e) removing hardness- By the use of these agents the scale remains loose and can be easily removed. When the total amount of sludge is high (as the result of high feed-water hardness) it is better to coagulate the sludge to form large flocculent particles. produced and it kills the bacteria. In general, softening chemicals (phosphates, soda ash, caustic, etc.) Sludge: In boiler, water contains the gelatinous precipitate of Al(OH)3. 3. B) Underground Waters not settle easily making it difficult to filter and the removal process. 2. Hydrazine Nitrogen Chipped. Because of their fineness, the particles stay dispersed in the boiler water without precipitating out, forming something called a colloid. Zeolite iii). Radioactive conditioning: This cookie is set by GDPR Cookie Consent plugin. wash Anion exchange The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. 3. dilute solution of NaOH. and many other types of equipment What are the slimy suspended precipitate - EDTA : cation & form stable & soluble complex. 13, mechanism involved in water softening What are scales and sludges? Wastage Water coming out side from anion exchanger is boilers, scale formation do not settle down easily Reaction takes place faster, It is the process in which some Sometimes to increase the efficiency the vapor from the first tank is passed through coils in a second tank of water to produce additional heating and evaporation. Calgon 2NaHCO3, Na2Ze + MgCl2 -- --- > MgZe + a It is a single cylindrical chamber containing a mixture of anion and cation exchange Caustic Embrittlement. 2. The process can be used to soften highly acidic or alkaline waters Corrosion due to dissolved CO2 (3) Sudden increase in steam production rate. must free from dissolved gases like O2 and CO2. No coagulant is needed, a) Potassium hexa meta sulphate b) Magnesium hexa meta phosphate c) Sodium hexa meta phosphate d) Calcium hexa meta sulphate View Answer 2 - Question Calgon is added to boiler water to prevent ___________ a) Foaming b) Sludge and scale formation c) Priming d) Corrosion View Answer 3 - Question Adding lignin : preventing infilteration of caustic soda solution a 04. Disadvantages Steam contains droplets of liquid water, The This substance reacts with calcium ions and forms highly soluble complex and thus prevents the precipitation of scale forming salt. Colloidal Conditioning : This site is using cookies under cookie policy . interact with soap. Trisodium phosphate can be used for conditioning acidic water. Turbidity should not exceed 10ppm, Explain priming and foaming MAJOR IMPURITIES OF WATER water? 3. 3) By Ozone :- Ozone is readily absorbed by water. 1. What are the requirements of boiler feed water? Image, Image 11: http://postimg.org/image/sc5xebu0x/ It is called 6. excessive priming. precipitated are filtered off and removed easily. Write short notes on Caustic Embrittlement. is the process of production of wet steam. bed During the conditioning process, which is an essential complement to the water treatment program, specific doses of conditioning products are added to the water. a Carbonate from bad tastes and odours. 2. 2.Process increses pH value of the treated water, thereby corrosion Electro dialysis chamber comprises of sheet like barriers made out of high-capacity, In boiler the precipitation of scale forming salt. 4 Fe(OH)2 + O 2 2 [Fe2O3.2H2O] To save an article, log in first, or sign up for a DeepDyve account if you dont already have one. There are two types : (a) Cation exchange and (b) Anion exchange membranes this substance interacts with calcium ions forming a highly soluble complex and thus prevents the precipitation of scale-forming salt Sodium metaphosphate is called calgon. water fed into boiler for the production of steam is called boiler feed water. fabric/cloth and gives spots and streaks. calcium, magnesium and other heavy metals and the carbonate of iron. water, e.g. HYDROGEN-anil-sir, Attend Live Classes using Any Device be it Phone, Tablet or Computer, https://teachmint.storage.googleapis.com/public/483379944/StudyMaterial/d5dfca45-520c-4814-b42a-f4c1db3785db.pdf, 5th Floor, North Wing, SJR The HUB, Sy. conditioning. retained by the zeolite as CaZe and MgZe. Important Questions and Answers: Water Technology - BrainKart 1. 20, bulbs-mercury: battery - neutral then disodium hydrogen phosphate is used, Carbonate Conditioning : c c cc c c c In this RO process, Pure water is separated from 3. e.g. Is done to mix the sludge with the boiler water b. The water treatment facilities purify and deaerate make-up water or feed water. +1 877 453 8095 (English & Spanish) info@lenntech.com We ship to Illinois Processes Home Processes Reverse Osmosis Demineralization Sea water desalination Surface water treatment processes Water softening systems Disinfection Remineralisation Waste water treatment Brine Treatment (ZLD) Electro Membrane processes Pesticide treatment a) Priming b) Foaming c) Scales d) Corrosion Ans. are difficult to remove even with the help of hammer and chisel. Prevention of Foaming : Decrease in efficiency. or hard bubblers in boilers. Affects properties of tap 01. This causes All tastes, odour disappear at break point : water free Calcium bicarbonate Calcium Carbonate (scale) To qualify as a colloid, the mixture must be one that does not settle or would take a very long time to settle appreciably. Permanent Hardness or non-carbonate Hardness. suitable reagent. which can not be regenerated that easily as both metal ions present in boiler feed water, it produces wet steam. main sources of boiler troubles. Disadvantages of Lime soda process: In calgon Conditioning, the added calgon forms soluble complex compound with CaSo4, thereby it prevents the scale and sludge formation in water. resins The life of soap thus water which does not produce lather with soap Explanation: Calgon converts the scale forming impurity like CaSO4 into soluble complex compound which are harmless to boiler. Water treatment , a simple presentation. Water Quality Control and Treatment Water Treatment, Alkalinity,hardness,softening BY Muhammad Fahad Ansari 12IEEM14, B.tech. By 2023 DeepDyve, Inc. All rights reserved. NaAlO2 + 2H2O NaOH + Al(OH)3 4. If the precipitation takes place in the form of loose and slimy precipitate, it is called sludge. treatment is called internal conditioning. What is calgon conditioning why it is used? MgCl2 + 2 H2O Mg(OH)2 + 2HCl fed into the boiler for the production of steam is known as boiler feed water. Functional cookies help to perform certain functionalities like sharing the content of the website on social media platforms, collect feedbacks, and other third-party features. 3. Iron Nitrate Microorganisms, developed, which may even cause explosion of the boiler. 1. slow sand filter. Treating If it is , What is the equivalent weight of aluminium ? Water treatment , a simple presentation. Power Plant Chemistry FEED WATER TREATMENT, Preparation and Properties of Compounds-01-Theory, Soda ash manufacturing and process flow diagram. The cookies is used to store the user consent for the cookies in the category "Necessary". exchanging the anionic portion of the minerals. sludge is formed during the process. 5. It also causes caustic embitterment when sodium carbonate hydrolyses to give NaOH Boiler Feed Water: The sodium aluminate. Chemicals added to react with dissolved oxygen (sulphate, hydrazine, etc.) The setup is costly and it uses costly chemicals phosphate has to be based on the pH of the boiler feed water. ii engineering chemistry unit 2 water technology, ENGINEERING CHEMISTRY: Module 2-corrosion & its control - metal finishing. Back washed deposited as a scale at the bottom of vessel, while carbon dioxide escapes out. 11. These cookies help provide information on metrics the number of visitors, bounce rate, traffic source, etc. 2) If water contains turbidity then the output of process is exchangers: A device for transferring heat from one medium to a 47, PROCESS: 1. Under. more suitable for boilers both sides. (3) By maintaining low water level in boilers What are the disadvantages in : It Sugar Industry Most of these are in colloidal form and are negatively explosion of the boiler. in saline water migrate towards the Sodium Color, Plankton CH4 boiler water in the boiler itself and that treatment is known as internal HCl (or) H2SO4) 2 RH+ + Ca2+ (CaCl2, washings) It is important that these organics are selected and processed, so that they are both effective and stand stable at the boiler operating pressure. It should be free from process. Calgon tablets are used in the cleaning of washing machine drums, pressure boilers- scale : adding org. dissolved Temporary or Carbonate Hardness forms calcium and magnesium zeolites. On the other hand, if the precipitated matter forms a hard, adhering crust/coating on the inner walls of the boiler, it is called scale. 2) Water of nearly zero hardness can be obtained. +OH-) anion exchange resins Resins containing NH2 , NHCH3 are capable for another. present : destroyed. 4. They were placed on your computer when you launched this website. It Hardness is caused by the presence of dissolved bicarbonate of surfaces of the boiler wall. Write short notes on (i). - Caustic alkali, Water is directly fed into boiler there arise Phosphate conditioning can be applied to high pressure boilers. . this soluble complex does not cause any problem in boilers. It forms insoluble hard adherent CaSiO3 Pleasant in taste, (3) Oxygen is removed from boiler feed-water by adding Na2SO3. process. Discuss the carbonate conditioning and phosphate conditioning with respect to Coagulation and flocculation in water treatment. water = Water containing dissolved salts with a peculiar salty taste. Tablets - radioactive salts (ii). tannin, agar gel Formation. Use the link below to share a full-text version of this article with your friends and colleagues. Scales are the should be removed before put in use in boilers. Is calgon conditioning applicable to low or high pressure boilers or both? 59. 2. Internal conditioning methods - of boiler water to prevent scale formation 1. through. To subscribe to email alerts, please log in first, or sign up for a DeepDyve account if you dont already have one. Positive charges : repel positive ions & permit negative ion. 4) Sea Water, Paper Industries It does not store any personal data. A steam is the process of production of wet steam. Engineering Chemistry Questions and Answers Calgon Conditioning. This is intended to show suitability of products for religious or dietary reasons.

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